Unidentified Halon-2402 emissions in East Asia are driving the global trend

Abstract: Halon-2402 (1,2‑dibromotetrafluoroethane, H-2402) is a potent ozone‑depleting substance and greenhouse gas whose global production has been banned under the Montreal Protocol since 2010, while the use of recovered or recycled stocks remains permitted for essential uses. Although these controls led to nearly two decades of declining atmospheric abundances, recent observations indicate renewed emissions. 

Here, we present the first observation-based regional emission estimates of H-2402 in East Asia for 2008–2023, derived using high-frequency measurements at Gosan, South Korea, and a Bayesian inversion framework. While most AGAGE stations measure background mole fractions or intermittent low-level increases, Gosan exhibits increasingly frequent and intense pollution events, revealing growing regional emissions. We find that East Asia accounted for most global H-2402 emissions in recent years, with particularly sharp increases in Japan and the Vladivostok region of Russia. Since 2015, regional emissions from East Asia have effectively driven the global emission trend, reversing the long-term decline. These emissions are spatially linked to petrochemical infrastructure, ship-repair activity, and military decommissioning sites, suggesting releases from legacy halon banks rather than new production. Cumulative emissions from East Asia between 2008 and 2023 reached ~52 Gg CFC-11-equivalent emissions. 

These findings imply a tangible delay in ozone layer recovery and underscore the urgent need for strengthened monitoring, transparent reporting, and verifiable management of remaining H-2402 stocks under the Montreal Protocol.